TY - JOUR

T1 - Recent advances in crystalline oxidopolyborate complexes of d-block or p-block metals: structural aspects, syntheses and physical properties

AU - Xin, Shu-Sheng

AU - Zhou, Ming-Hua

AU - Beckett, Michael

AU - Pan, Chun-Yang

N1 - Invited contribution to special issue: Frontiers of Boron Chemistry in 21sh Century: From Fundamental Science to Applications

PY - 2021/6/22

Y1 - 2021/6/22

N2 - Crystalline materials containing hybrid inorganic–organic metal borates (complexes with oxidoborate ligands) display a variety of novel framework building blocks. The structural aspects of these hybrid metallaoxidoborates containing Cd(II), Co(II), Cu(II), Ga(III), In(III), Mn(II), Ni(II) or Zn(II) metal centers are discussed in this review. The review describes synthetic approaches to these hybrid materials, their physical properties, their spectroscopic properties and their potential applications.

AB - Crystalline materials containing hybrid inorganic–organic metal borates (complexes with oxidoborate ligands) display a variety of novel framework building blocks. The structural aspects of these hybrid metallaoxidoborates containing Cd(II), Co(II), Cu(II), Ga(III), In(III), Mn(II), Ni(II) or Zn(II) metal centers are discussed in this review. The review describes synthetic approaches to these hybrid materials, their physical properties, their spectroscopic properties and their potential applications.

KW - borates

KW - coordination compounds

KW - inorganic–organic hybrids

KW - oxidoborate ligands

U2 - 10.3390/molecules26133815

DO - 10.3390/molecules26133815

M3 - Review article

C2 - 34206683

VL - 26

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 13

M1 - 3815

ER -