Standard Standard

Synthesis and characterization of templated pentaborate(1-) salts: X-ray structure of [(2-HOCH2CH2)C4H7NMeH][B5O6(OH)4]·0.3H2O. / Jones, Charlotte; Beckett, Michael; Coles, Simon J. et al.
In: Phosphorus, Sulfur and Silicon and the Related Elements, Vol. 191, No. 4, 01.08.2016, p. 628-630.

Research output: Contribution to journalArticlepeer-review

HarvardHarvard

Jones, C, Beckett, M, Coles, SJ, Davies, R & Horton, PN 2016, 'Synthesis and characterization of templated pentaborate(1-) salts: X-ray structure of [(2-HOCH2CH2)C4H7NMeH][B5O6(OH)4]·0.3H2O', Phosphorus, Sulfur and Silicon and the Related Elements, vol. 191, no. 4, pp. 628-630. https://doi.org/10.1080/10426507.2015.1128921

APA

CBE

MLA

VancouverVancouver

Jones C, Beckett M, Coles SJ, Davies R, Horton PN. Synthesis and characterization of templated pentaborate(1-) salts: X-ray structure of [(2-HOCH2CH2)C4H7NMeH][B5O6(OH)4]·0.3H2O. Phosphorus, Sulfur and Silicon and the Related Elements. 2016 Aug 1;191(4):628-630. Epub 2016 Feb 6. doi: 10.1080/10426507.2015.1128921

Author

Jones, Charlotte ; Beckett, Michael ; Coles, Simon J. et al. / Synthesis and characterization of templated pentaborate(1-) salts: X-ray structure of [(2-HOCH2CH2)C4H7NMeH][B5O6(OH)4]·0.3H2O. In: Phosphorus, Sulfur and Silicon and the Related Elements. 2016 ; Vol. 191, No. 4. pp. 628-630.

RIS

TY - JOUR

T1 - Synthesis and characterization of templated pentaborate(1-) salts: X-ray structure of [(2-HOCH2CH2)C4H7NMeH][B5O6(OH)4]·0.3H2O

AU - Jones, Charlotte

AU - Beckett, Michael

AU - Coles, Simon J.

AU - Davies, Richard

AU - Horton, Peter N.

PY - 2016/8/1

Y1 - 2016/8/1

N2 - The synthesis of pyrrolidinium pentaborate(1-) and four substituted pyrrolidinium pentaborate(1-) salts from B(OH)3 in aqueous solution are reported. Characterization (Infrared, nuclear magnetic resonance, and single-crystal X-ray power diffraction) of [(2-HOCH2CH2)C4H7NH2] [B5O6(OH)4]0.3H2O is described in detail. The cation is the largest of the five pyrrolidinium cations studied. A consequence of this is that its solid-state structure has anion–anion interactions (αααγ), which are different from the other four (αααβ) structures. There are also stabilizing cation–anion H-bond interactions.

AB - The synthesis of pyrrolidinium pentaborate(1-) and four substituted pyrrolidinium pentaborate(1-) salts from B(OH)3 in aqueous solution are reported. Characterization (Infrared, nuclear magnetic resonance, and single-crystal X-ray power diffraction) of [(2-HOCH2CH2)C4H7NH2] [B5O6(OH)4]0.3H2O is described in detail. The cation is the largest of the five pyrrolidinium cations studied. A consequence of this is that its solid-state structure has anion–anion interactions (αααγ), which are different from the other four (αααβ) structures. There are also stabilizing cation–anion H-bond interactions.

KW - Pentaborate(1-)

KW - H-bonds

KW - pyrrolidinium

KW - X-ray structure

KW - oxidoborate

U2 - 10.1080/10426507.2015.1128921

DO - 10.1080/10426507.2015.1128921

M3 - Article

VL - 191

SP - 628

EP - 630

JO - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

SN - 1042-6507

IS - 4

ER -