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Synthesis and XRD study of an C2-linked bis(quaternary ammonium) pentaborate: [Me3NCH2CH2NMe3][B5O6(OH)4]2. / Beckett, Michael; Coles, Simon J.; Horton, Peter N.; Rixon, Thomas.

In: Phosphorus, Sulfur and Silicon and the Related Elements, 20.06.2019.

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Beckett, M., Coles, S. J., Horton, P. N., & Rixon, T. (2019). Synthesis and XRD study of an C2-linked bis(quaternary ammonium) pentaborate: [Me3NCH2CH2NMe3][B5O6(OH)4]2. Phosphorus, Sulfur and Silicon and the Related Elements. https://doi.org/10.1080/10426507.2019.1631308

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Beckett, Michael ; Coles, Simon J. ; Horton, Peter N. ; Rixon, Thomas. / Synthesis and XRD study of an C2-linked bis(quaternary ammonium) pentaborate: [Me3NCH2CH2NMe3][B5O6(OH)4]2. In: Phosphorus, Sulfur and Silicon and the Related Elements. 2019.

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TY - JOUR

T1 - Synthesis and XRD study of an C2-linked bis(quaternary ammonium) pentaborate: [Me3NCH2CH2NMe3][B5O6(OH)4]2

AU - Beckett, Michael

AU - Coles, Simon J.

AU - Horton, Peter N.

AU - Rixon, Thomas

N1 - This article has been accepted for publication in Phosphorus, Sulfur and Silicon and the Related Elements, published by Taylor & Francis. This is an original manuscript / preprint of an article published by Taylor & Francis in [JOURNAL TITLE] on [date of publication], available online: http://www.tandfonline.com/[Article DOI]

PY - 2019/6/20

Y1 - 2019/6/20

N2 - The synthesis and characterization of a C2 (ethane) linked bis(trimethylammonium) pentaborate salt, [Me3NCH2CH2NMe3][B5O6(OH)4]2 (1), is reported . Compound 1 has been characterized by 1H, 11B, and 13C NMR Spectroscopy, IR spectroscopy, thermal (TGA/DSC) analysis, and single-crystal X-ray diffraction. There are two independent crystallographic pentaborate(1-) anions in the solid-state structure and these link by H-bonds at -sites into a centrosymmetric tetrameric chain. These chains are crossed-linked by R22(8) H-bond motifs to -sites of neighbouring pentaborate tetrameric units. The [Me3NCH2CH2NMe3]2+ cations are located between these tetrameric pentaborate(1-) units.

AB - The synthesis and characterization of a C2 (ethane) linked bis(trimethylammonium) pentaborate salt, [Me3NCH2CH2NMe3][B5O6(OH)4]2 (1), is reported . Compound 1 has been characterized by 1H, 11B, and 13C NMR Spectroscopy, IR spectroscopy, thermal (TGA/DSC) analysis, and single-crystal X-ray diffraction. There are two independent crystallographic pentaborate(1-) anions in the solid-state structure and these link by H-bonds at -sites into a centrosymmetric tetrameric chain. These chains are crossed-linked by R22(8) H-bond motifs to -sites of neighbouring pentaborate tetrameric units. The [Me3NCH2CH2NMe3]2+ cations are located between these tetrameric pentaborate(1-) units.

KW - Oxidoborate, pentaborate(1-0, Polybortae, 1,2-bis(trimethylammonium)ethane; X-ray strcture

U2 - 10.1080/10426507.2019.1631308

DO - 10.1080/10426507.2019.1631308

M3 - Article

JO - Phosphorus, Sulfur and Silicon and the Related Elements

T2 - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

SN - 1042-6507

ER -