Research Portal

Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations

Research output: Contribution to journal › Article › peer-review

Standard Standard

Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations. / Beckett, M.A.; Coles, S.; Davies, R.A. et al.
In: Dalton Transactions, Vol. 44, 10.03.2015, p. 7032-7040.

Research output: Contribution to journal › Article › peer-review

HarvardHarvard

Beckett, MA, Coles, S, Davies, RA, Horton, P & Jones, CL 2015, 'Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations', Dalton Transactions, vol. 44, pp. 7032-7040. https://doi.org/10.1039/C5DT00248F

APA

Beckett, M. A., Coles, S., Davies, R. A., Horton, P., & Jones, C. L. (2015). Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations. Dalton Transactions, 44, 7032-7040. https://doi.org/10.1039/C5DT00248F

CBE

Beckett MA, Coles S, Davies RA, Horton P, Jones CL. 2015. Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations. Dalton Transactions. 44:7032-7040. https://doi.org/10.1039/C5DT00248F

MLA

Beckett, M.A. et al. "Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations". Dalton Transactions. 2015, 44. 7032-7040. https://doi.org/10.1039/C5DT00248F

VancouverVancouver

Beckett MA, Coles S, Davies RA, Horton P, Jones CL. Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations. Dalton Transactions. 2015 Mar 10;44:7032-7040. doi: 10.1039/C5DT00248F

Author

Beckett, M.A. ; Coles, S. ; Davies, R.A. et al. / Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations. In: Dalton Transactions. 2015 ; Vol. 44. pp. 7032-7040.

RIS

TY - JOUR

T1 - Pentaborate(1-) salts templated by substituted pyrrolidinium cations: synthesis, structural characterization, and modelling of solid-state H-bond interactions by DFT calculations

AU - Beckett, M.A.

AU - Coles, S.

AU - Davies, R.A.

AU - Horton, P.

AU - Jones, C.L.

PY - 2015/3/10

Y1 - 2015/3/10

N2 - The synthesis and characterization of a series of pentaborate(1−) salts of substituted pyrrolidinium cations [C4H8NH2][B5O6(OH)4] (1), [C4H8NMe2][B5O6(OH)4] (2) [C4H8NMeH][B5O6(OH)4] (3), [(2-CH2OH)C4H7NH2][B5O6(OH)4] (4) is reported. All compounds were characterized by single-crystal XRD studies with 3 (1/2CH3COCH3) and 4 (1/2H2O) solvated. TGA/DSC analysis of the pentaborates 1–4 showed that they thermally decomposed in air at 800 °C to 2.5 B2O3, in a 2 step process involving dehydration (

AB - The synthesis and characterization of a series of pentaborate(1−) salts of substituted pyrrolidinium cations [C4H8NH2][B5O6(OH)4] (1), [C4H8NMe2][B5O6(OH)4] (2) [C4H8NMeH][B5O6(OH)4] (3), [(2-CH2OH)C4H7NH2][B5O6(OH)4] (4) is reported. All compounds were characterized by single-crystal XRD studies with 3 (1/2CH3COCH3) and 4 (1/2H2O) solvated. TGA/DSC analysis of the pentaborates 1–4 showed that they thermally decomposed in air at 800 °C to 2.5 B2O3, in a 2 step process involving dehydration (

U2 - 10.1039/C5DT00248F

DO - 10.1039/C5DT00248F

M3 - Article

VL - 44

SP - 7032

EP - 7040

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

ER -