Triborate and pentaborate salts of non-metal cations derived from N-substituted piperazines: synthesis, structural (XRD) and thermal properties
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The synthesis and characterization of a triborate salt, [H2N(CH2CH2)2NH2][B3O3(OH)4]2 (1), and four pentaborate salts, [H2N(CH2CH2)2NH][B5O6(OH)4] (2a), [MeHN(CH2CH2)2NH][B5O6(OH)4] (2b), [MeHN(CH2CH2)2NMe][B5O6(OH)4] (2c) and [Me2N(CH2CH2)2NMe2][B5O6(OH)4]2 (2d) are described. TGA and DSC analysis (in air, 25–1000 °C) indicate that triborate 1 decomposes to B2O3via a multistage process, with the first stage (
Original language | English |
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Pages (from-to) | 15185-15191 |
Journal | RSC Advances |
Volume | 3 |
DOIs | |
Publication status | Published - 17 Jun 2013 |
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